Amazing Spider-Man (1963)

 1st appearance of the Lizard! Spider-man vs. the Lizard cover and story by Stan Lee and Steve Ditko!

2nd appearance of the Vulture, who starred in Spider-man Homecoming!  Spider-man vs. the Vulture cover and story by Stan Lee and Steve Ditko!

1st appearance of the Enforcers, and the Big Man. Spider-man cover and story by Stan Lee, Steve Ditko, and Jack Kirby

1st appearance of the Enforcers, and the Big Man. Spider-man vs. the Enforcers by Stan Lee, Steve Ditko, and Jack Kirby

1st appearance of Kraven the Hunter! 2nd appearance of the Chameleon!  1st mention of Mary Jane Watson! Spider-man vs. Kraven the Hunter and the Chameleon by Stan Lee and Steve Ditko!

2nd appearance of the Green Goblin! Spider-man, Human Torch, and Green Goblin cover and story! Stan Lee and Steve Ditko, copy b

2nd appearance of the Green Goblin! Spider-man, Human Torch, and Green Goblin cover and story! Stan Lee and Steve Ditko

2nd appearance of the Green Goblin!  Spider-man vs the Torch and the Goblin cover and story, Classic Stan Lee and Steve Ditko cover and story!

1st appearance of Ned Leeds! Spider-man vs Sandman cover and story, Fantastic Four, Daredevil, and the Avengers appear, Stan Lee and Steve Ditko!

Spider-man vs the Sandman, the Human Torch, and the Enforcers by Stan Lee and Steve Ditko!

1st appearance of Mac Gargan (the Scorpion) in cameo on last page! Spider-man, Human Torch, and the Sandman cover and story

Spidey caught between the Human Torch and the Beetle! Spider-man cover and story by Stan Lee and Steve Ditko!

1st appearance of Princess Python!

1st appearance of Princess Python. Spider-man vs. the Circus of Crime cover and story by Stan Lee, Steve Ditko, and Jack Kirby

1st appearance of Princess Python, Amazing Spider-man vs. the Circus of Crime cover and story

3rd appearance of the Green Goblin! Spider-man and Green Goblin cover and story! Stan Lee and Steve Ditko

3rd appearance of the Green Goblin! Spider-man and Green Goblin cover and story! Stan Lee and Steve Ditko

2nd appearance of Mysterio!  Classic Ditko cover and art! Looks better, but has a bit of flaking at top edge.

2nd appearance of Mysterio, Spider-man vs. Mysterio cover and story by Stan Lee and Steve Ditko

1st appearance of Mary Jane Watson (face not shown). 1st appearance of the Spider-Slayer and Professor Spencer Smythe.

4th appearance of the Green Goblin!  1st Crime Master

4th appearance of the Green Goblin!  1st Crime Master Spider-man cover and story by StanLee and Steve Ditko

1st appearance of the Molten Man. Spider-man vs. Molten Man cover and story by Stan Lee, Steve Ditko, and Jack Kirby

1st appearance of the Molten Man. Spider-man vs. Molten Man cover and story by Stan Lee, Steve Ditko, and Jack Kirby