Amazing Spider-man #4 CGC 9.6
1st appearance of Silk! Spider-man cover and story
Detective Comics #577 NM+ (9.6)
Batman cover and story with art by Todd McFarlane
Amazing Spider-Man #347 (Newsstand) VF/NM (9.0)
Spider-man vs Venom cover and story
Amazing Spider-Man #346 (Newsstand) VF/NM (9.0)
Spider-man vs Venom cover and story
Amazing Spider-Man #275 NM- (9.2)
Spider-man vs. Hobgoblin cover and story, origin of Spider-man retold
Amazing Spider-Man #260 NM (9.4)
Spider-man vs. Hobgoblin cover and story, likely improvable
Amazing Spider-Man #259 NM+ (9.6)
Spider-man vs. Hobgoblin cover and story, origin of Mary Jane Watson
Uncanny X-Men #213 CGC 9.6
Classic Wolverine vs Sabretooth cover by Alan Davis, X-Men vs Marauders story, Psylocke joins the team
Uncanny X-Men #317 NM (9.4)
1st appearance of Blink, art by Joe Madueira, X-Men cover and story, might make 9.6
Incredible Hulk #282 VF (8.0)
She-Hulk, Hulk, Iron Man, and the Leader story, Avengers appear
Incredible Hulk and Wolverine #1 VF+ (8.5)
Reprints the 1st 2 appearances of Wolverine (Hulk #180, 181) as well as a Wolverine vs. Hercules story from Marvel Treasury #26
Amazing Spider-Man #315 NM (9.4)
Spider-man vs. HydroMan cover and story with Todd McFarlane art, Venom cover and appearance
Amazing Spider-Man #260 NM+ (9.6)
Spider-man vs. Hobgoblin cover and story
Amazing Spider-Man #239 NM (9.4)
1st Hobgoblin vs Spider-man battle, 1st full appearance of the Hobgoblin
X-Men #221 CGC 9.6
1st appearance of Mr. Sinister, Havok vs. Wolverine cover, X-Men vs Marauders story
Detective Comics #504 (Newsstand edition) NM- (9.2)
Batman vs Joker cover and story
Giant Size Super-Heroes #1 VF/NM (9.0)
Spider-man vs. Morbius and the Man-Wolf cover and story
Amazing Spider-Man #239 (Newsstand edition) NM+ (9.6)
1st Hobgoblin vs Spider-man battle, 1st full appearance of the Hobgoblin,
Wolverine #4 (Newsstand edition) NM (9.4)
Wolverine cover and story by Chris Claremont and Frank Miller
Amazing Spider-Man #361 (Newsstand edition) CGC 9.4
1st appearance of Carnage who appears in Venom 2, Let There be Carnage and is almost certain to show up in the MCU! Spider-man vs Carnage cover and story
Wolverine #154 NM (9.4)
Deadpool vs Wolverine cover and story! Rob Liefeld art!
Detective Comics #570 NM (9.4)
Batman vs Joker and Catwoman cover and story, Alan Davis art