Batman #359 CGC 9.6
1st cover appearance of Killer Croc, 1st full appearance, Joker, Penguin, Riddler, and Scarecrow cover, Batman vs. Killer Croc story
Batman #442 CGC 9.8
Classic Robin cover and story by7 George Perez, 1st appearance of Tim Drake in Robin costume, Batman, Nightwing, and Robin vs. Two Face story
Ms. Marvel #1 F/VF (7.0)
Carol Danvers gets her own series, 1st appearance as Ms. Marvel, might improve a little
Fantastic Four #67 CGC 8.5
1st appearance of Adam Warlock (Him), conclusion of the origin of Warlock! Fantastic Four cover and story
Captain America #169 CGC 9.4
1st appearance of Moonstone in cameo, Captain America cover and story, Falcon and Black Panther appear
Adventures of the Fly #1 VG/F (5.0)
the Fly cover and story by Jack Kirby and Joe Simon
Double Life of Private Strong #1 VG+ (4.5)
1st appearance of the Shield and the Fly, Kirby art
Strange Tales #114 VG (4.0)
1st appearance of the Captain America since the Golden Age, actually the Acrobat in a Captain America costume! Doctor Strange vs Baron Mordo! Stan Lee and Jack Kirby and Steve Ditko!
Fantastic Four #211 NM+ (9.6)
1st appearance of Terrax, Fantastic Four cover and story, white pages, John Byrne art
Avengers #59 F/VF (7.0)
1st appearance of Yellowjacket! Avengers cover and story
Batman #457 NM (9.4)
Tim Drake officially becomes Robin, Batman and Robin vs. the Scarecrow cover and story
Transformers #10 NM- (9.2)
1st appearance of Constructicons, Transformers cover and story
Transformers #6 NM (9.4)
1st appearance of Josie Beller, Transformers cover and story
Flash #137 F/VF (7.0)
1st Silver Age appearance of Vandal Savage! Flash of Earth 1 vs. Flash of Earth 2 cover and story
Silver Surfer #44 VF/NM (9.0)
1st appearance of the Infinity Gauntlet, Thanos, Silver Surfer, and Drax cover and story
Incredible Hulk #377 NM (9.4)
1st appearance of Professor Hulk, in which the Hulk retains all his strength, but also the brain of Banner, Dale Keown art
Ghost Rider #2 F (6.0)
1st appearance of the Son of Satan (Damon Hellstrom), Ghost Rider vs Satan and the Witch Woman cover and story
Avengers #144 F- (5.5)
1st appearance of Hellcat, who later becomes Tigra!
Flash #137 VF (8.0)
1st Silver Age appearance of Vandal Savage! Flash of Earth 1 vs. Flash of Earth 2 cover and story
Thor #137 VF/NM (9.0)
1st appearance of Ulik! Thor cover and story, looks nicer but has some tanning
Thor #127 VF/NM (9.0)
1st Pluto, Thor cover and story, Stan Lee and Jack Kirby, I think this will make 9.2, but just rather be conservative
Superman's Girlfriend Lois Lane #19 NM- (9.2)
1st Imaginary story (Elseworlds), Superman and Lois Lane cover and story, very nice copy,
Peter Porker, the Spectacular Spider-ham #1 VF/NM (9.0)
This character has gained tremendous popularity since appearing in the Edge of Spider-verse movie.