Detective Comics #570 CGC 9.8
Batman vs Joker and Catwoman cover and story, Amazing Alan Davis cover and art
Batman #359 CGC 9.6
1st cover appearance of Killer Croc, 1st full appearance, Joker, Penguin, Riddler, and Scarecrow cover, Batman vs. Killer Croc story
Batman #442 CGC 9.8
Classic Robin cover and story by7 George Perez, 1st appearance of Tim Drake in Robin costume, Batman, Nightwing, and Robin vs. Two Face story
Batman #497 CGC 9.8
The story that inspired the movie The Dark Knight Rises, Batman vs Bane cover and story, Bane breaks Batman's back, Kelley Jones cover
Amazing Spider-Man #362 (Silver ) NM- (9.2)
Spidey vs Venom and Carnage cover and story, 2nd print, silver background edition, improvable
Amazing Spider-Man #317 NM (9.4)
Spider-man vs. Venom cover and story with Todd McFarlane art
Batman Annual #16 NM- (9.2)
Classic Joker cover by Sam Keith, Batman vs. Joker story
Batman Annual #14 NM (9.4)
Classic Neal Adams Two Face cover, Batman vs. Two Face story
Batman #457 NM (9.4)
Tim Drake officially becomes Robin, Batman and Robin vs. the Scarecrow cover and story
Amazing Spider-Man #500 NM (9.4)
Spider-man and Mary Jane vs. everybody cover by J Scott Campbell
Amazing Spider-Man #374 NM+ (9.6)
Spidey vs Venom cover and story, probably a press away from 9.8
Amazing Spider-Man #345 NM+ (9.6)
Spider-man vs Boomerang cover and story, Venom & Cletus Kasady appear including how Kasady gets the symbiote
Amazing Spider-Man #321 NM (9.4)
Spider-man, Silver Sable, and Paladin cover and story with Todd McFarlane art
Amazing Spider-Man #320 NM- (9.2)
Spider-man, Silver Sable, and Paladin cover and story with Todd McFarlane art
Amazing Spider-Man #319 NM- (9.2)
Spider-man vs. the Rhino, the Scorpion, and BlackLash cover and story with Todd McFarlane art, likely improvable
Transformers #10 NM- (9.2)
1st appearance of Constructicons, Transformers cover and story
Transformers #6 NM (9.4)
1st appearance of Josie Beller, Transformers cover and story
Silver Surfer #44 VF/NM (9.0)
1st appearance of the Infinity Gauntlet, Thanos, Silver Surfer, and Drax cover and story
Punisher #1 VF/NM (9.0)
First issue of the Punisher's first ongoing series!
Justice League of America #261 VF+ (8.5)
last issue, Vixen cover and story
Incredible Hulk #377 NM (9.4)
1st appearance of Professor Hulk, in which the Hulk retains all his strength, but also the brain of Banner, Dale Keown art